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Bromination of Tetrachlorobenzobarrelene: Polyhalogenated Benzobicyclics
Benzobarrelene bromination Wagner-Meerwein rearrangement polyhalogenides
2010/4/9
The low and high temperature bromination reaction of tetrachlorobenzobarrelene was studied and the possible role of a neighboring group in rearrangements was investigated. New polyhalogenated benzobic...
Bromination of Benzonorbornadiene Using a Mixture of Sodium Bromide and Sodium Perborate at High Temperatures
Bromination benzonorbornadiene high temperature bromination sodium perborate
2010/4/22
Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement. How...
Bromination of 2,3-Dibromobenzobarrelene at Different Conditions: Highly Brominated Benzobicyclic Systems
benzobarrelene high temperature bromination Wagner-Meerwein rearrangement and poly-bromides
2010/4/22
The electrophilic addition of bromine to 2,3-dibromobenzobarrelene at 10oC led to the formation of completely rearranged products in high yield. Bromination of 2,3-dibromobenzobarrelene with molecular...